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When it comes to Hollywood leading men, looks are often just as important as acting chops. And that is definitely the case off-screen, when heartthrobs are photographed at big-budget premieres, at glamorous parties or even just out grocery shopping. A handsome face and sharp clothes can boost a reputation—or, more importantly, a future box-office take. By 2013, the best-dressed men in Hollywood have become a mix of rising stars and industry veterans, but they all have one thing in common: they know how to cut a dashing figure on the red carpet.